Stabilization and Isolation of Radical Cation and Dication of a Tetrathiafulvalene Derivative Functionalized with Amino Groups
2020
The radical cation and dication salts of a tetrathiafulvalene (TTF) derivative functionalized with two amino groups have been successfully stabilized and isolated by specifically chemical oxidation using polyfluoroalkoxyaluminate weak coordinating anion, [Al(ORF)4]− (ORF = OC(CF3)3). These compounds were characterized by UV-Vis-NIR absorption spectroscopy, 1H NMR, EPR, and X-ray single crystal diffraction, respectively. Comprehensive research on their structure-property relation in conjunction with theoretical calculations has been carried out.
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
35
References
0
Citations
NaN
KQI