A novel and convenient protocol for synthesis of alpha-haloacrylates.
2008
A novel and convenient protocol for synthesis of α-haloacrylates starting from phosphonium ylide and aldedyde or alcohol was described. Halodimethylsulfonium halide was used for the first time in halogenation of phosphonium ylide. Good yield as well as a high Z/E ratio were shown in representative cases, and an umpolung dimethyl sulfide−ylide species might be involved as an intermediate.
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