Crystallographic Characterization of Ti2C2@D3h(5)-C78, Ti2C2@C3v(8)-C82, and Ti2C2@Cs(6)-C82: Identification of Unsupported Ti2C2 Cluster with Cage-Dependent Configurations.

Fullerene cages are ideal hosts to encapsulate otherwise unstable metallic clusters to form endohedral metallofullerenes (EMFs). Herein, a novel Ti2C2 cluster with two titanium atoms bridged by a C...