A Total Synthesis Trilogy: Calicheamicin γ1I, Taxol®, and Brevetoxin A

K. C. Nicolaou,Christopher R. H. Hale,Christian Nilewski

A Total Synthesis Trilogy: Calicheamicin γ1I, Taxol®, and Brevetoxin A

2012

K. C. Nicolaou
Christopher R. H. Hale
Christian Nilewski

Detailed behind-the-scenes accounts of the total syntheses of calicheamicin γ1I, Taxol®, and brevetoxin A are discussed with particular emphasis placed on strategies and tactics employed in these campaigns. DOI 10.1002/tcr.201200005

Keywords:

Brevetoxin A
Total synthesis
Organic chemistry
Stereochemistry
Calicheamicin
Chemistry

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