Crystal Structure of (E)-2-(3,3,3-trifluoroprop-1-en-1-yl)aniline
2018
The molecule of the title compound, C9H8F3N, adopts an E configuration with respect to the C=C double bond. The dihedral angle between the benzene ring and the prop-1-enyl group is 25.4 (3)°. In the crystal, molecules are linked via pairs of N—H⋯F hydrogen bonds into inversion dimers with an R22(16) ring motif. The dimers are linked by C—H⋯N hydrogen bonds, forming a ribbon structure along the b-axis direction. The ribbons are linked by N—H⋯π and C—H⋯π interactions, generating a three-dimensional network.
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