Hydride Migration from Silicon to an Adjacent Unsaturated Imino Carbon: Intramolecular Hydrosilylation

1,3-Hydride shift from silicon to an adjacent imino carbon (“intramolecular hydrosilylation”) is observed in the reaction of MeSiHCl2 with O-trimethylsilyl-N-(alkylidenimino)imidates [RC(OSiMe3)═NN...