New Porphyrin Dendrimers with Fluorenyl-based Connectors: A Simple Way to improving the Optical Properties over Dendrimers featuring 1,3,5-Phenylene Connectors

2020 
Two new meso-tetrafluorenylporphyrin-cored dendrimers 1 and 2 have been synthesized and characterized. The peripheral fluorenyl units of these dendrimers are linked to the central tetrafluorenylporphyrin (TFP) core by original fluorene-based connectors instead of the more classic 1,3,5-phenylene unit. Selected linear and non-linear optical (LO and NLO) properties were determined for these dendrimers via absorption or emission studies and by two-photon excited fluorescence (TPEF) measurements. Dendrimer 1, which has a conjugated and quite rigid structure, exhibits a significantly higher two-photon absorption (2PA) cross-section than dendrimer 2, presenting a non-conjugated and more flexible structure, as well as better luminescence and singlet oxygen activation quantum yields. Both dendrimers exhibit higher 2PA cross-sections than several closely related TFP-based dendrimers previously characterized. However, among them, dendrimer 1 is the only one outperforming all these compounds in terms of 2PA brightness and 2PA oxygen sensitization. Thus, the new type of connector (or dendrimeric node) introduced in 1 appears quite appealing for the design photosensitizers aimed at theranostic uses in the future
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