Global Analysis of the Mechanical Properties of Organic Crystals

Organic crystals, although widely studied, have not been considered nascent candidate materials in the engineering design. Here we summarize the reported mechanical properties of organic crystals reported over the past three decades, and we establish a global mechanical property profile that can be used to predict and identify mechanically robust organic crystals. Being composed of light elements, organic crystals populate a narrow region in the mechanical property-density space between soft, disordered organic materials and stiff, ordered materials. Two subsets of extraordinarily stiff and hard organic crystalline materials were identified and rationalized by the normalized number density, strength and directionality of their intermolecular interactions. We conclude that the future light-weight, soft, all-organic components in devices should capitalize on the combination of long-range structural order and softness as the greatest asset of organic single crystals.