Hydroamination of Terminal Alkynes with Secondary Amines Catalyzed by Copper: Regioselective Access to Amines.
2015
A series of tertiary amines (III) and (V) is readily prepared by a copper-catalyzed solvent-free hydroamination of alkynes (I) with secondary amines (II) and (IV) followed by reduction of intermediate (E)-enamines.
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