Self-assembly of a mixed-valence FeII–FeIII tetranuclear star

Darunee Sertphon,Phimphaka Harding,Keith S. Murray,Boujemaa Moubaraki,Nicholas F. Chilton,Stephen Hill,Jonathan Marbey,Harry Adams,Casey G. Davies,Guy N. L. Jameson,David J. Harding

Self-assembly of a mixed-valence FeII–FeIII tetranuclear star

2018

Darunee Sertphon
Phimphaka Harding
Keith S. Murray
Boujemaa Moubaraki
Nicholas F. Chilton
Stephen Hill
Jonathan Marbey
Harry Adams
Casey G. Davies
Guy N. L. Jameson
David J. Harding

A unique self-assembled mixed-valence FeII–FeIII tetranuclear star has been comprehensively characterised showing a large magnetic anisotropy at the peripheral FeII centres, ferromagnetic coupling between the iron centres and field-induced SMM behaviour.

Keywords:

Photochemistry
Self-assembly
Magnetic anisotropy
Ferromagnetism
Chemistry
Valence (chemistry)
Chemical physics
Cluster (physics)
Magnetization
Coupling
Nanomagnet

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