Goodbye to S2− in aqueous solution
2018
New Raman spectra of Na2S dissolved in hyper-concentrated NaOH(aq) and CsOH(aq) cast serious doubt on the widely-assumed existence of S2−(aq). To avoid conceptual and practical problems with sulfide equilibria in numerous applications, S2−(aq) should be expunged from the chemical literature. Thermodynamic databases involving sulfide minerals also need careful revision.
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
16
References
31
Citations
NaN
KQI