Dielectric relaxation and magnetodielectric effect in the spinel NiCr2O4

Abstract Single phase NiCr2O4 has been successfully prepared by sol–gel technique. Characterization of crystal and morphology exhibits the tetragonal structure and homogeneous growth with regular crystalline shape. Large dielectric constant of ~2447 is observed at room temperature. The relaxation behavior below room temperature is confirmed through measurements of dielectric constant, dielectric loss, electric modulus and impedance depended on frequency or temperature. The analysis through equivalent circuit simulation demonstrates the influence of grains at low temperature and the common contribution of grains and grain boundaries at high temperature. Moreover, the change in dielectric response indicates the presence of magnetodielectric coupling effect. Two different mechanisms are considered to control the magnetodielectric coupling, yielding the positive and negative coupling coefficient at different temperature ranges. The intrinsic magnetoelectric coupling gives rise to the frequency independent magnetodielectric behavior at low temperature. As temperature increases above 150 K, the large magnetodielectric coupling coefficient depended on frequency is contributed by the Maxwell-Wagner effect. The negative value of magnetodielectric coupling coefficient is attributed to the leakage current. Therefore, both mechanisms of Maxwell-Wagner and leakage are competing as a function of frequency, which results in the coefficient crossover at room temperature. Such features bring NiCr2O4 a step closer to potential applications in areas such as magnetic field sensors, actuators and others.