Regioselective Ene-Type Allylic Chlorination of Electron-Rich Alkenes by Activated DMSO
2017
A simple protocol involving the activation of DMSO by chlorotrimethysilane is described for the chemoselective chlorination of polyprenoids. The proposed protocol provides a versatile and scalable alternative to existing routes for accessing useful synthetic synthons for the synthesis of complex terpenoids.
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