Enhanced corrosion resistance of laser aided additive manufactured CoCrNi medium entropy alloys with oxide inclusion

Abstract The electrochemical corrosion behavior of laser aided additive manufactured (LAAMed) CoCrNi medium entropy alloys (MEAs) with different oxide inclusion level was investigated in 3.5 wt.% NaCl solution. Different from the 316 L stainless steel, no pitting appeared on the LAAMed CoCrNi within the test regime used in this study. The LAAMed sample with a higher oxide inclusion level demonstrated lower corrosion current density and higher charge transfer resistance, implying a more compact passive film. After holding in the solution at 0.2 VSCE for 30 mins, the passive films formed on the LAAMed CoCrNi MEAs have similar thickness and dominant constituent (i.e. Cr2O3 and Cr(OH)3). More oxides in the LAAMed CoCrNi MEA could facilitate the formation of a compact passive film, which leads to superior corrosion resistance.