Control of the Enantioselectivity by Keto Bile Acid Derivatives in the Epoxidation of Alkenes with Oxone.
2004
Abstract The asymmetric epoxidation of unfunctionalized olefins has been achieved using 3-keto bile acids as optically active inducers and Oxone. Opposite enantioselectivities can be obtained depending on the specific substitution of the bile acids.
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