N-Acyl-Glutarimides: Effect of Glutarimide Ring on the Structures of Fully Perpendicular Twisted Amides and N-C Bond Cross-Coupling.

N-Acyl-glutarimides have emerged as the most reactive precursors for N–C(O) bond cross-coupling reactions to date, wherein the reactivity is driven by ground-state-destabilization of the amide bond...