Catalytic Dicyanative [4 + 2] Cycloaddition Triggered by Cyanopalladation Using Ene—Enynes and Cyclic Enynes with Methyl Acrylate.

Shigeru Arai,Yuka Koike,Hirohiko Hada,Atsushi Nishida

Catalytic Dicyanative [4 + 2] Cycloaddition Triggered by Cyanopalladation Using Ene—Enynes and Cyclic Enynes with Methyl Acrylate.

2011

Shigeru Arai
Yuka Koike
Hirohiko Hada
Atsushi Nishida

The title reactions allow easy and stereoselective access to highly substituted isoindole and indan derivatives, tricyclic ring systems of type (VI), and other fused cyclohexenes.

Keywords:

Isoindole
Cyclohexenes
Methyl acrylate
Cycloaddition
Organic chemistry
Ene reaction
Chemistry
Stereoselectivity
Catalysis

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