A New π-conjugated 1,7-diphenoxy-perylene bisimide: Synthesis, characterization, photophysical and electrochemical properties
2018
Abstract A novel π-conjugated 1,7-diphenoxy-perylene bisimide (perylene diimides, PDIs) ( 4 ) was synthesized starting from 1,7(6)-diphenoxyperylene-3,4,9,10-tetracarboxylic bisanhydride ( 3 ). N,N'-bis(4-hydroxyphenyl)-perylene-3,4,9,10-tetracarboxy bisimide ( 1 ) was synthesized and characterized also for the comparison between a non-bay substituted symmetrical perylene diimide and the bay substituted symmetrical perylene diimide with the same substituents at the PDI imide positions. Positive and weak solvatochromic effect for the compounds 3 and 4 was apparently observed in polar media. The absolute positions of LUMO and HOMO values of 1 and 3 in solution were −3.775 eV/−6.035 eV and −3.971 eV/−6.041, respectively. The HOMO, LUMO and E g values for the compound 4 were not calculated due to the non-resolved reduction peaks most probably due to aggregation.
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