A Luminescent Silver(I) Metal‐Organic Framework with New (4,6)‐Connected Topology Based on Mixed Tetrachlorotereph­thalate and 2,2′‐Bipyridine Ligands

A silver(I) coordination polymer with mixed 2,3,5,6-tetrachloro-1,4-benzenedicarboxylate (BDC-Cl4) and 2,2′-bipyridine (2,2′-bpy) ligands, [Ag2(BDC-Cl4)(2,2′-bpy)]n (1), was synthesized and structurally characterized. Compound 1 features a robust three-dimensional (3D) network, exhibiting a new (4,6)-connected net with the Schlafli symbol of (32·42·5·6)2(32·42·52·87·9·10). The photoluminescence properties of 1 were investigated in the solid state at room temperature.