Self-Assembly Supramolecular Polymer by Anti-Electrostatic Anion-Anion and Halogen Bonding Interactions

We report here the generation of a self-assembly supramolecular polymer in which the cooperative action of anti-electrostatic anion-anion and halogen-bonding interactions serve as a powerful driven force to form large supramolecular polymers. DOSY-NMR, DLS, TEM, SEM and X-ray experiments evidence the formation of supramolecular structures in solution and solid state.