Insulating ferromagnet with giant coercivity in monoclinic double perovskite La2CuIrO6

Insulating ferromagnets with high TC are required for many new magnetic devices but are very rare. More complexity arises when strongly correlated 3d ions coexist with strongly spin-orbit coupled 5d ones in a double perovskite. Here, we performed the structural, magnetic, and density functional theory (DFT) study of such double perovskite La2CuIrO6. A new P21/n structure phase is found according to the comprehensive analysis of x-ray, Raman scattering and phonon spectrum. The magnetization reveals a ferromagnetic (FM) transition at TC = 62 K and short range FM order in higher temperature range. A giant coercivity is found as high as HC~11.96 kOe at 10K, which in combination with the negative trapped field results in the magnetization reversal in the ZFC measurement. The DFT calculations confirm the observed FM state and suggest La2CuIrO6 is a Mott insulating ferromagnet assisted by the SOC. This work highlights the unusual FM insulating state and the potential application of such novel 3d-5d double perovskites.