Comparative Study of Potentially Jeff = 0 Ground State Iridium(V) in SrLaNiIrO6, SrLaMgIrO6, and SrLaZnIrO6
2017
Abstract: A series of polycrystalline double perovskites SrLaBIrO6 (B = Ni, Mg, Zn) containing Ir5+ (5d4) has been synthesized by solid state reactions, and structural, magnetic and electronic properties were investigated. The isotypic fully ordered double perovskites crystallize in space group P21/n and show semiconducting behavior with estimated band gaps of approximately 0.2 eV for SrLaNiIrO6 and SrLaZnIrO6, and 0.4 eV for SrLaMgIrO6. SrLaNiIrO6 is an antiferromagnet with a Neel temperature of 74 K (eff = 3.3 B, W = -90 K) while SrLaMgIrO6 and SrLaZnIrO6 are weakly paramagnetic. All title compounds exhibit a temperature-independent contribution to the measured magnetic susceptibility which supports the notion for a van-Vleck-type response originating from the Ir5+ (5d4, Jeff = 0) ions.
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