Reactive, intumescent, halogen‐free flame retardant for polypropylene

A reactive, intumescent, halogen-free flame retardant, 2-({9-[(4,6-diamino-1,3,5-triazin-2-yl)amino]-3,9-dioxido-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecan-3-yl}oxy)ethyl methacrylate (EADP), was synthesized through a simple three-step reaction from phosphorus oxychloride, pentaerythritol, hydroxyethyl methacrylate, and melamine. EADP exhibited excellent thermal stability and char-forming ability, as revealed by thermogravimetric analysis (TGA) and scanning electron microscopy (SEM). The TGA results show that the temperature at 5% weight loss was 297.8°C and the char yield at 700°C was 51.75%. SEM observation revealed that the char showed a continuous and compact surface and a cellular inner structure with different sizes. Composite of polypropylene (PP) with a 25 wt % addition of EADP (PP/EADP25) passed the UL-94 V-0 rating and showed a limiting oxygen index value of 31.5. Compared with those of neat PP, the flexural strength and modulus values of PP/EADP25 were somewhat improved, the tensile strength was basically unchanged, and the notched Izod impact strength was slightly decreased. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 40054.