Selectfluor-mediated mono-C–H activation: The syntheses of mono- ortho -substituted anilides
2018
Abstract The C–H activation of aryl amide using readily available Pd(OAc) 2 in the presence of selectfluor is reported. The highly mono-selective introduction of sp 2 hybridized functional groups have been realized. A broad range of aryl-, alkenyl- and keto-aryl amides were prepared using unactivated coupling partners under mild conditions.
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