CdSe/ZnS QD@CNT nanocomposite photocathode for improvement on charge overpotential in photoelectrochemical Li-O2 batteries
2018
Abstract Li-ion batteries play a significant role in portable electronic devices in the running world. However, the limited energy density still needs to be improved for the growing future. Hence, we developed a photocathode nanocomposite material composed of Cadmium Selenide/Zinc Sulfide Quantum Dots with Carbon nanotube (CdSe/ZnS QD@CNT) for an efficient and tunable performance of the photoelectrochemical Li–O 2 battery system to overcome the key issue of overpotential. The QD and CNT networks can provide efficient transportation paths of the electron–hole pairs and the O 2 gas and lithium ions, respectively. The charging voltage of the photoelectrode is 2.65–4.0 V; therefore, decreased overpotential was due to efficient oxidation of Li 2 O 2 by photoexcited electron–hole pairs by using QDs, resulting in a long-term operational stability over 100 cycles. On the basis of the advantages, the QDs exhibit efficient potential in Li–O 2 batteries.
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