Nano-raman spectroscopy with metallized atomic force microscopy tips on strained silicon structures

In this paper, intensity enhancements of the Raman signal from strained silicon films utilizing the tip enhanced Raman spectroscopy (TERS) effect are reported. Specially shaped metallized atomic force microscopy tips have been prepared by sputter deposition of thin silver films onto sharpened quartz tips and subsequent focused ion beam (FIB) modification. Raman signal enhancements of more than 20%, which are attributed to the strained silicon film of 70nm thickness only, have been obtained due to approaching the TERS tips the laser spot. On samples with patterned trench structures prepared by FIB milling, lateral sample scans have been performed. These scans revealed a resolution of strained silicon lines with center-to-center distances below 250nm, well below the classical optical diffraction limit. Based on an analysis of the stress state in the strained silicon structures, relaxation effects close to the trench edges have been investigated. The described approach of nano-Raman spectroscopy is promising...