Highly active and selective hydrodeoxygenation of oleic acid to second generation bio-diesel over SiO2-supported CoxNi1−xP catalysts

Abstract Bio-fuels have been proposed as an ideal alternative fuel to conventional fossil fuel due to the advantages of renewability and low pollution. Herein, to greatly enhance the catalytic activity and selectivity of for the production of second generation biodiesel, designed and developed five kinds of catalysts with different ratios (3/1, 5/3, 1/1, 3/5, 1/3) of Co to Ni. The composite catalyst was characterized by XRD, XPS and HRTEM techniques. The activity and selectivity of the catalyst were evaluated by the hydrodeoxidization of oleic acid. It was found that the hydrodeoxygenation activity and selectivity of Co x Ni 1−x P/SiO 2 catalyst was closely related to the proportion of Co/Ni. The selectivity of C 17 followed the decreasing order: 3/5 > 1/3 ≈ 1/1 > 5/3 > 3/1 (Co/Ni ratios). Clearly, among all the samples, the catalyst with 3/5 Co/Ni ratio exhibits the best conversion rate and selectivity of 97% and 86% for the production of C 17 , respectively. The high activity and selectivity of Co x Ni 1−x P/SiO 2 were dominantly attributed to the synergistic effects and the uniform dispersion of Co and Ni species on the SiO 2 supports. In particular, the Co x Ni 1−x P/SiO 2 shows the more advantages than the high activity for Ni-based catalysts and high selectivity for Co-based catalysts. It is expected that the catalyst has the great potential to be used in the practical industrial production.