Antiferromagnetic coupling in copper(II)porphyrin dimers linked by copper(II) or palladium(II) ion

Mary-Ambre Carvalho,Hervé Dekkiche,Sébastien Richeter,Corinne Bailly,Lydia Karmazin,Declan McKearney,Daniel B. Leznoff,Guillaume Rogez,Bertrand Vileno,Sylvie Choua,Romain Ruppert

Antiferromagnetic coupling in copper(II)porphyrin dimers linked by copper(II) or palladium(II) ion

2019

Mary-Ambre Carvalho
Hervé Dekkiche
Sébastien Richeter
Corinne Bailly
Lydia Karmazin
Declan McKearney
Daniel B. Leznoff
Guillaume Rogez
Bertrand Vileno
Sylvie Choua
Romain Ruppert

The synthesis of porphyrin dimers linked by metal ions is described and the X-ray structure of two new dimers is presented. As previously shown for diamagnetic metal ions, strong electronic interac...

Keywords:

Photochemistry
Ion
Antiferromagnetism
Copper
Palladium
Coupling
Porphyrin
Chemistry
Metal ions in aqueous solution
Diamagnetism
antiferromagnetic coupling

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