Synthesis of N-Acetyl-3,3a,4,8b- and -1,3a,4,8b-tetrahydrocyclopenta[b]indoles from N- and 2-(Cyclopent-2-en-1-yl)anilines.

D. A. Skladchikov,R. S. Buranbaeva,A. A. Fatykhov,S. P. Ivanov,Rail R. Gataullin

Synthesis of N-Acetyl-3,3a,4,8b- and -1,3a,4,8b-tetrahydrocyclopenta[b]indoles from N- and 2-(Cyclopent-2-en-1-yl)anilines.

2013

D. A. Skladchikov
R. S. Buranbaeva
A. A. Fatykhov
S. P. Ivanov
Rail R. Gataullin

N-Acylation of anilines (I) leads to the formation of a diastereoisomeric mixture of atropisomers (III) which is separable at room temperature for (IIIb).

Keywords:

Atropisomer
Organic chemistry
Chemistry

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