Thiocyanation of indoles
1978
Treatment of indole, 2-phenylindole, 2-methylindole, and ethyl indole-2-carboxylate with thiocyanogen in acetic acid at 0° afforded the corresponding 3-thiocyanatoindoles in quantitative yields, whereas similar treatment of 3-methyl-2-phenylindoles and 2,3-diphenylindoles gave the corresponding 6-thiocyanatoindoles in high yields.
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