Concise synthesis of an enantiopure bicyclic pyrazinone as constrained peptidomimetic building block.
2012
A concise synthetic route has been developed for the preparation of a constrained peptidomimetic pyrazinone building block. From hydroxy-L-lysine, the desired pyrazinone is obtained in 43% overall yield (6 steps) via an efficient deprotection–double cyclization sequence.
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