Hetarynes IX: Reactions of some bromoethoxypyridines with lithium piperidide in piperidine
2010
Reactions of 3-bromo-4-ethoxypyridine and 2-bromo-6-ethoxypyridine with lithium piperidide in piperidine have been investigated.
It was found that in these compounds both substituents when occupying positions 2,4 or 6 are replaced by the piperidino group without rearrangements occurring. From 3-bromo-4-ethoxypyridine some 2,4-dipiperidinopyridine is formed as an additional product, probably via 4-piperidino-2,3-pyridyne as an intermediate.
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