Endowing a Light-Inert Aqueous Surfactant Two-Phase System with Photoresponsiveness by Introducing a Trojan Horse

The ability to modulate the phase behavior of an aqueous surfactant two-phase (ASTP) system reversibly with light is of great importance in both fundamental and applied science. Thus far, most of the light-responsive ASTP systems are based on covalent modification of the component molecules. In this article, we, for the first time, achieve photoresponsiveness in a light-inert ASTP system by physically introducing a phototrigger with the aid of a Trojan horse. The ASTP system formed from sodium laurate (SL) and dodecyltributylammonium bromide (DBAB) does not show light responsiveness by physically mixing a light-responsive azobenzene compound, 2-(4-(phenyldiazenyl)phenoxy)acetate sodium (Azo). However, in the presence of the host–guest complex SL@β-CD formed from β-CD and sodium laurate (SL), the ASTP turns quickly into a homogeneous suspension under visible light, which recovers to the original ASTP state again under 365 nm UV irradiation. Because the SL@β-CD complex exists harmonically with the ASTP syst...