A Rapid Ionization Change in the Nebular-Phase Spectra of the Type Ia SN 2011fe

We present three new spectra of the nearby Type Ia supernova (SN Ia) 2011fe covering $\approx 480-850~$days after maximum light and show that the ejecta undergoes a rapid ionization shift at $\sim 500~$days after explosion. The prominent [FeIII] emission lines at $\approx 4600~$\r{A} are replaced with the permitted FeI+FeII blends at $\sim 4400~$\r{A} and $\sim 5400~$\r{A}. The $\approx 7300~$\r{A} feature, which is produced by [FeII]+[NiII] at $\lesssim 400~$days after explosion, is replaced by broad ($\approx \pm 15\,000~\rm{km}~\rm{s}^{-1}$) symmetric [CaII] emission. The change in emission characteristics is likely due to the temperature in the inner ejecta dropping below the level needed to populate the high-ionization FeIII transitions. This ionization shift corresponds to a distinct temperature and density in the ejecta and may be useful as a probe of the ejecta's temporal evolution. Models predict this ionization transition occurring $\sim 100~$days later than what is observed which we attribute to clumping in the ejecta. Finally, we discuss the reliability of [CaII] as an ejecta diagnostic feature.