Conformation-Dependent Spin Relaxation Behaviors of 6-Oxoverdazyl Radical Single Crystals
2020
The
molecular conformation and packing mode of organic radicals
are vital to achieving distinctive electronic, spin relaxation, and
magnetic properties. Herein two organic radicals, B2P and B4P, are
developed by attaching a 6-oxoverdazyl radical at different peripheral
positions of [1]benzothieno[3,2-b][1]benzothiophene
(BTBT). B2P single crystals exhibit a typical herringbone packing
mode, whereas B4P single crystals display a classic brick-layer stacking
structure. Moreover, two crystalline phases, B4P-Y and B4P-R, are
observed in B4P crystals owing to the rotational isomerization. Because
of the distinct molecular conformation and packing structures, the
spin relaxation behaviors of the two 6-oxoverdazyl radicals are significantly
different, and B4P-Y with a distorted conformation exhibits a longer
spin relaxation time.
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