Flapping Peryleneimide as a Fluorogenic Dye with High Photostability and Strong Visible‐Light Absorption
2020
Flapping fluorophores (FLAP) with a flexible 8π ring are rapidly gaining attention as a versatile photofunctional system. Here we report a highly photostable "flapping peryleneimide" with an unprecedented fluorogenic mechanism based on a bent-to-planar conformational change in the S 1 excited state. The S 1 planarization induces an electronic configurational switch, almost quenching an inherent fluorescence (FL) of peryleneimide moieties. However, the FL quantum yield is remarkably improved with a prolonged lifetime by a slight environmental change. This fluorogenic function is realized by sensitive π-conjugation design, as a more π-expanded analogue does not show the planarization dynamics. With strong visible-light absorption, the FL lifetime response synchronized with the flexible flapping motion is useful for the latest optical techniques such as FL lifetime imaging microscopy (FLIM).
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