The chemistry of ferrocenesulfonyl fluoride revealed.
2021
The first general route toward polysubstituted ferrocenesulfonyl fluorides is described. Merging deprotometallations, ‘halogen dance’ reaction, Sonogashira, Suzuki–Miyaura and Negishi cross-couplings with SuFEx chemistry allowed original ferrocenes of an unprecedented diversity to be obtained.
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