Urea-Catalyzed Vinyl Carbocation Formation Enables Mild Functionalization of Unactivated C–H Bonds

Alex L. Bagdasarian,Stasik Popov,Benjamin Wigman,Wenjing Wei,Woojin Lee,Hosea M. Nelson

Urea-Catalyzed Vinyl Carbocation Formation Enables Mild Functionalization of Unactivated C–H Bonds

2020

Alex L. Bagdasarian
Stasik Popov
Benjamin Wigman
Wenjing Wei
Woojin Lee
Hosea M. Nelson

Herein we report the 3,5-bistrifluoromethylphenyl urea-catalyzed functionalization of unactivated C–H bonds. In this system, the urea catalyst mediates the formation of high-energy vinyl carbocatio...

Keywords:

Carbocation
Urea
Catalysis
Chemistry
Organic chemistry
reaction conditions
Surface modification

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