Transforming Co3O4 nanosheets into porous N-doped CoxOy nanosheets with oxygen vacancies for the oxygen evolution reaction
2019
Abstract Cobalt oxides have been widely investigated as promising replacements for noble metal-based catalysts for oxygen evolution reaction (OER). Herein, we, for the first time, have obtained porous Co x O y nanosheets with N-doping and oxygen vacancies by etching Co 3 O 4 nanosheets with NH 3 plasma. Comparing with the pristine Co 3 O 4 nanosheets (1.79 V), the porous Co x O y nanosheets with N-doping and oxygen vacancies have a much lower potential of 1.51 V versus RHE to reach the current density of 10 mA cm −2 . The obtained sample has a lower Tafel slope of 68 mV dec −1 than the pristine Co 3 O 4 nanosheets (234 mV dec −1 ). The disclosed Co 2+ , which is responsible for the formation of active sites (CoOOH), N-doping and oxygen vacancies, gives rise to better performance of OER.
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