Synthesis of substituted naphthalenes from α-substituted ketones and 1,2-bis(halomethyl)benzenes including a rearrangement aromatization of benzo[c]oxepine
2014
Abstract An efficient and practical method for the synthesis of cyano, sulfonyl and phosphoryl substituted naphthalene derivatives via the rearrangement aromatization of benzo[ c ]oxepine has been developed. The system holds the advantages of metal catalysts free, and mild reaction conditions.
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