Palladium/copper-catalyzed decarbonylative heteroarylation of amides via C–N bond activation
2019
A novel strategy for the synthesis of 2-arylated oxazole derivatives via palladium/copper-catalyzed decarbonylative heteroarylation of amides via C–N bond activation by ground-state destabilization is reported. This transformation shows good functional group tolerance and delivers the versatile 2-arylated oxazole derivatives in moderate to good yields. This transformation provides unique and efficient strategies for converting readily available amides and the precursor carboxylic acids into valuable chemicals.
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