Emission characteristics of polychlorinated, polybrominated and mixed polybrominated/chlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs, PBDD/Fs, and PBCDD/Fs) from waste incineration and metallurgical processes in China

Abstract Typical thermal processes are common sources of polychlorinated, polybrominated and mixed polybrominated/chlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs, PBDD/Fs, and PBCDD/Fs); however, very few reports have investigated their coemission. To clarify the emission characteristics of these DD/Fs, two municipal waste incinerators (MWIs), three hazardous waste incinerators (HWIs), one cement kiln coprocessing municipal waste incinerator (CMWI), one secondary copper smelter (SCu), and one iron and steel sintering smelter (ISS) in China were investigated. In total, 17 congeners of PCDD/Fs, 14 congeners of PBDD/Fs, and 12 congeners of PBCDDs in stack flue gases from these thermal processes were analyzed using a high-resolution gas chromatograph/high-resolution mass spectrometer (HRGC/HRMS) in this study. PCDD/Fs, PBDD/Fs and PBCDD/Fs were detectable in all samples, with total concentrations of 911-5.15 × 103 pg/Nm3 (80.2–414 pg TEQ/Nm3). The concentrations of each DD/F were similar within the same type of facility and varied among different types of facilities. The contributions of PBDD/Fs and PBCDD/Fs to the total concentrations exceeded that of PCDD/Fs in some cases, such as in HWIs and SCu. In general, the ∑Cl4-7 CDFs and ∑Cl7-8 CDDs, 1,2,3,4,6,7,8-HpBDF, and 1-B-2,3,7,8-TeCDD and 2-B-1,3,7,8-TeCDD were the dominant congeners in the PCDD/F, PBDD/F, and PBCDD/F mass concentrations, respectively. Several other congeners present at low mass concentrations, such as 1,2,3,4,7,8-HxBDF, have potential as major contributors to the TEQs due to their high toxic equivalency factors. These results reveal the necessity of synergistically inhibiting the occurrences of PCDD/Fs, PBDD/Fs, and PBCDD/Fs from these sources and provide valuable information for use in the source identification of these pollutants in the environment.