Binder-assisted electrostatic spray deposition of LiCoO2 and graphite films on coplanar interdigitated electrodes for flexible/wearable lithium-ion batteries

Abstract Flexible battery technologies have lately attracted much attention in the field of wearable electronics. A coplanar interdigitated electrode design encompasses the merits of bending tolerance and increased kinetics owing to shortened diffusion length for applications in these batteries. However, the fabrication of a coplanar patterned electrode remains a challenge because the conventional slurry casting method is unsuitable. In this study, we present a new process to prepare an interdigitated coplanar electrode using binder-assisted electrostatic spray deposition (ESD) without vacuum or high-cost techniques. Using the binder-assisted ESD method, it is possible to deposit powder of any type or size. Moreover, this approach is versatile and universal for application to the design of any coplanar cell configuration and is achieved using a binder-assisted dispersion method based on a commercially available active material. A full-cell flexible battery is fabricated with a coplanar interdigitated electrode using a LiCoO2 cathode and graphite anode. The low cost, simplicity, efficacy, and flexibility of this method are very promising attributes in the design and fabrication of flexible/wearable batteries.