Cohalogenation of Allyl and Vinylsilanes using Polymer-bound Haloate(I)-Reagents

Electronic Conference on Synthetic Organic Chemistry, September 1-30, 2000, (Paper B0001).Received: 6 November 2000; in revised form 7 January 2001 / Accepted: 8 January 2001 / Published: 16 January 2001Abstract: Polymer-supported electrophilic halogenate(I) complexes 2 and 3 promote smooth addition to vinyl and allylsilanes without loss of the silyl group. In conjunction with Amberlyst A26 (OH