Exceptionally Strong Electronic Coupling in Crystalline Perylene Diimides via Tuning
2011
The first series of core-unsubstituted perylene diimides exhibiting a long and tunable λmax in the solid state has been prepared. Unprecedentedly long λmax values have been achieved, which implies the presence of exceptionally strong electronic coupling. A tuning mechanism on the basis of competing subunits has been proposed.
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