Efficient and Reproducible Monolithic Perovskite/Organic Tandem Solar Cells with Low-Loss Interconnecting Layers

Summary Perovskite solar cells (PSCs) and organic photovoltaics (OPVs) have both undergone rapid development recently. The composition and molecular tunability of perovskite and organic semiconductors enable a large material pool with different band gaps and various physical characters, giving feasibility to construct perovskite/organic tandem solar cells (TSCs). Here, we developed a semi-empirical model, rationally selected the best available material combination, and successfully demonstrated the efficient and reproducible TSCs benefiting from their complementary band gaps and orthogonal processing solvents. Featuring with all-thermally evaporated low-loss interconnecting layers (ICLs), our 2-termimal (2T) monolithic perovskite/organic TSCs deliver high reproducibility with power conversion efficiency (PCE) narrowly distributed between 20% and 20.6% (certified as 19.54%). In addition to the promising efficiency, the UV sensitivity of OPVs is eliminated in the tandem structure, demonstrating its advantage on device stability. Those results unfold significant potentials of perovskite/organic tandem devices as reproducible and cost-effective structures to achieve high-performance TSCs.