A Ring of C2H in the Molecular Disk Orbiting TW Hya

We have used the Submillimeter Array to image, at ?1.?5 resolution, C2H emission from the circumstellar disk orbiting the nearby (D = 54 pc), ?8 Myr-old, ?0.8 classical T Tauri star TW Hya. The SMA imaging reveals that the C2H emission exhibits a ring-like morphology. Based on a model in which the C2H column density follows a truncated radial power-law distribution, we find that the inner edge of the ring lies at ?45 AU, and that the ring extends to at least ?120 AU. Comparison with previous (single-dish) observations of C2H emission indicates that the C2H molecules are subthermally excited and, hence, that the emission arises from the relatively warm ( K), tenuous ( cm?3) upper atmosphere of the disk. Based on these results and comparisons of the SMA C2H map with previous submillimeter and scattered-light imaging, we propose that the C2H emission most likely traces particularly efficient photo-destruction of small grains and/or photodesorption and photodissociation of hydrocarbons derived from grain ice mantles in the surface layers of the outer disk. The presence of a C2H ring in the TW Hya disk hence likely serves as a marker of dust grain processing and radial and vertical grain size segregation within the disk.