Hetero-Diels-Alder Reactions of Quinone Methides: the origin of the α-regioselectivity of 3-methylene-1,2,4-naphthotriones.

Maicon Delarmelina,Sabrina B. Ferreira,Fernando de C. da Silva,Vitor F. Ferreira,José Walkimar de M. Carneiro

Hetero-Diels-Alder Reactions of Quinone Methides: the origin of the α-regioselectivity of 3-methylene-1,2,4-naphthotriones.

2020

Maicon Delarmelina
Sabrina B. Ferreira
Fernando de C. da Silva
Vitor F. Ferreira
José Walkimar de M. Carneiro

The regioselective formation of α- and β-lapachone via Hetero-Diels-Alder reactions was investigated by experimental and computational approaches. The experimentally observed α-selectivity was expl...

Keywords:

Regioselectivity
Organic chemistry
Quinone
Methylene
diels alder
Chemistry

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