Efficient degradation of orange II by core shell CoFe2O4-CeO2 nanocomposite with the synergistic effect from sodium persulfate.

Abstract: Novel core shell CoFe2O4–CeO2 (CoFe–Ce) nanocomposite was synthesized and investigated as an efficient photocatalyst to activate sodium persulfate (Na2S2O8, PS) for orange Ⅱ (OⅡ) degradation. The CoFe–Ce nanocomposite was successfully designed and synthesized by a facile hydrothermal reaction followed by calcination and characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), ultraviolet–visible diffuse reflectance spectroscopy (UV–Vis DRS), and vibrating sample magnetometer (VSM). Compared with pure CoFe2O4 and CeO2, the photocatalytic efficiency of CoFe–Ce nanocomposite was significantly improved. Under the irradiation of visible light, the catalytic degradation efficiency of orange II could reach to 98.5% within 60 min. Additionally, the as-prepared material could be recycled for at least five times using magnetic separation ability of the nanocomposite, and during the cycling the dye degradation rate was almost unchanged. The active species produced during the degradation were studied by classical quenching experiments, and the different types of free radicals produced in the system were further confirmed by electron paramagnetic resonance (EPR) spectroscopy. This novel nanocomposite is expected to have potential application for degradation of organic pollutants in wastewater by utilizing solar energy.