Solvent-dependent luminescence behavior of a new charge-transfer Cu(I)-MOF: An experimental and theoretical investigation
2015
Abstract Herein we report the first charge-transfer metal–organic framework with open Cu(I)-sites, which exhibits intriguing solvent-dependent luminescence behaviors. An extended analysis of experimental and computational result indicates that strong metal–solvent bonding interaction plays a dominant role in the sensing of various solvents.
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